Issue 0, 1980

Capillary phenomena. Part 11.—Approximate treatment of the shape and properties of fluid interfaces of infinite extent meeting solids in a gravitational field

Abstract

The approximate expression involving modified Bessel functions, Z=(1 + cos Φ)½K0(X√2)/K1(X√2), has been obtained as the first integral of Laplace's equation of capillarity, relating the meridian ordinate Z to the abscissa X and the meridian angle Φ= arctan (dZ/dX), for holm meridians. Holm meridians are those having a vertical axis of symmetry and which begin at the asymptotic limit X→∞ when Z= 0 and extend to small X values, e.g., they represent a rod dipped in a large vessel containing a liquid.

Many of the features previously predicted, e.g., applied force maxima, for solid rods and cones dipping into a liquid can be obtained by the approximate treatment given, without resort to numerical computation.

Comparison with a treatment by Ferguson (1912) gives a useful mathematical approximation between zeroth- and first-order modified Bessel functions, K0(z)/K1(z)≈[1 +z–1]–½, which is accurate to 3.3 % for z= 0.5, 0.27 % for z= 2 and 0.01 % for z= 10. Comparison has also been made with the first-integral capillary approximations of Ferguson, Tsivinskii (1962) and James (1974).

The treatment has been extended to give second-integral approximations for holm meridians Z=Z(X). The Z ordinate is given above and X is given by evaluation of X=Xmin+X(Φ) K0(Xmin2)/K1(Xmin2) where X(Φ)={ln|tan [(Φ+ 180°)/4]|–2 sin (Φ/2)}/√2+ 0.376 77 and Xmin, which is a shape factor, is the value of X at the waist of a holm. Agreement with computed meridians (numerical integration) is excellent for Xmin > 1.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1980,76, 1419-1432

Capillary phenomena. Part 11.—Approximate treatment of the shape and properties of fluid interfaces of infinite extent meeting solids in a gravitational field

E. A. Boucher and T. G. J. Jones, J. Chem. Soc., Faraday Trans. 1, 1980, 76, 1419 DOI: 10.1039/F19807601419

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements