Titanium dioxide–electrolyte interface. Part 2.—Surface charge (titration) studies
Abstract
Surface charge–pH isotherms for TiO2 in K+, Li+, Mg2+ and tetramethylammonium electrolyte solutions are reported for a TiO2 colloid sample shown previously to be essentially holocrystalline and non-porous. The charge data are similar to other oxides with the exception of precipitated silica. The adsorption sequence obtained is Mg2+
Li+ > K+≃(CH3)4N+.
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