Rate constants at 298.2 K for the release of pyrrolidine from pentacyano(pyrrolidine)ferrate(II) have been measured under pseudo-first-order conditions and the effect of inert inorganic and alkylammonium salts on the kinetics were investigated. The observed order can be explained considering solute–solvent interactions which turn out to be operative in dissociative processes.
G. C. Pedrosa, N. L. Hernández, N. E. Katz and M. Katz, J. Chem. Soc., Dalton Trans., 1980, 2297 DOI: 10.1039/DT9800002297
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