Dynamic n.m.r studies have yielded accurate energy data for S and Se pyramidal inversion in complexes of type [PtXMe3(L–L)][X = Cl, Br, or I; L–L = MeE(CH2)nEMe, E = S or Se, n= 2 or 3]. The mechanism of the inversion process and the effects of atomic mass, ring size, and nature of halogen on the barrier energies are discussed.
E. W. Abel, A. R. Khan, K. Kite, K. G. Orrell and V. Šik, J. Chem. Soc., Dalton Trans., 1980, 1175 DOI: 10.1039/DT9800001175
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