Issue 6, 1980

Optimized synthesis and mechanism of formation of 2,4-dichloro-1,3-bis(dichlorophosphoryl)-2,4-dioxocyclodiphosph(V)azane from phosphoryl chloride and ammonium chloride

Abstract

Detailed investigation of the reaction between [NH4]Cl and an excess of POCl3 has established a procedure for isolation of the main product, the novel title cyclodiphosph(V)azane, and permitted the identification of three other reaction products, namely, pyrophosphoryl chloride, hexachlorocyclotriphosph(V)azene, and PPP-trichloro-N-dichlorophosphorylmonophosph(V)azene. A reaction mechanism is proposed which accounts for the formation of all four products.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1980, 851-853

Optimized synthesis and mechanism of formation of 2,4-dichloro-1,3-bis(dichlorophosphoryl)-2,4-dioxocyclodiphosph(V)azane from phosphoryl chloride and ammonium chloride

R. De Jaeger and D. R. Taylor, J. Chem. Soc., Dalton Trans., 1980, 851 DOI: 10.1039/DT9800000851

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