Thermal decomposition of 4-(2-azidobenzyl)-methoxycarbonylbenzene (1) and the triphenylmethyl analogue (2) gives azepinoindoles, by nitrene insertion into the electron-deficient benzene ring.
P. C. Hayes and G. Jones, J. Chem. Soc., Chem. Commun., 1980, 844a DOI: 10.1039/C3980000844A
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