Enthalpies and free energies of ligand addition to iron(II) porphyrins, as determined by variable-temperature electrochemistry, were linearly related to the ligand pKa, while the entropies remained constant.
K. M. Kadish and D. Schaeper, J. Chem. Soc., Chem. Commun., 1980, 1273 DOI: 10.1039/C39800001273
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