Issue 24, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

Resonance Raman spectrum of the mixed-valence anion-bridged complex Cs2[Pt(NO2)(NH3)Br2][Pt(NO2)(NH3)Br4]

Robin J. H. Clark  and  Mohamedally Kurmoo  

Abstract

The resonance Raman spectrum of the title complex with 568·2 nm excitation consists of eleven three-or-more-membered progressions, in nine of which the ν1, ν(BrPtIVBr), acts as the progression-forming mode; the results yield (among others)ω1= 179·0 ± 0·3 cm–1, x11=–0·39 ± 0·04 cm–1, and imply a substantial change in the PtIV–Br chain bond length (along with other structural changes) on excitation of the complex from the ground to the resonant (intervalence) excited state.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39800001258
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 1258-1259

Permissions

Request permissions

Resonance Raman spectrum of the mixed-valence anion-bridged complex Cs2[Pt(NO2)(NH3)Br2][Pt(NO2)(NH3)Br4]

R. J. H. Clark and M. Kurmoo, J. Chem. Soc., Chem. Commun., 1980, 1258 DOI: 10.1039/C39800001258

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements