N-4-Methoxybenzyl- and N-3,4-dimethoxybenzyl-aminoacetonitriles with both 2-aryl and N-alkyl substituents undergo O-demethylation and rearrangement with elimination of ammonia in concentrated sulphuric acid to give 1-aryl-N-alkylcyclohepta[c]pyrrol-6(2H)-ones.
R. D. Waigh, J. Chem. Soc., Chem. Commun., 1980, 1164 DOI: 10.1039/C39800001164
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