Issue 23, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

X-Ray crystal structure of two new mixed-valence copper cyanide complexes: unusual bi-co-ordinated copper(I) atoms in polymeric networks

Charles Kappenstein  and  Ulrich Schubert  

Abstract

The two mixed-valence compounds [Cu4I(CN)6CuII(NH3)2]n and [Cu3I(CN)5CuII(NH3)2(OH2)]n display polymeric networks in the solid state and show co-ordination numbers three and two for the copper(I) atoms and four or five for the copper(II) atoms.

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Article information

DOI
https://doi.org/10.1039/C39800001116
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 1116-1118

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X-Ray crystal structure of two new mixed-valence copper cyanide complexes: unusual bi-co-ordinated copper(I) atoms in polymeric networks

C. Kappenstein and U. Schubert, J. Chem. Soc., Chem. Commun., 1980, 1116 DOI: 10.1039/C39800001116

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