Issue 23, 1980

Asymmetric induction via co-ordination to Cr(CO)3; nucleophilic attack on acyclic carbenium ions

Abstract

Temporary complexation of (S)-(–)-1-phenylethanol by the Cr(CO)3 moiety allows the use of carbenium ions to bring about asymmetric transformations with a high degree of retention of configuration, even in open-chain compounds.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 1110-1112

Asymmetric induction via co-ordination to Cr(CO)3; nucleophilic attack on acyclic carbenium ions

S. Top, G. Jaouen and M. J. McGlinchey, J. Chem. Soc., Chem. Commun., 1980, 1110 DOI: 10.1039/C39800001110

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements