Reduction of CO by H2 using carbonyls of Fe, Ru, and Os in 2-methoxyethanol below 200 °C and 200 atm gives dimethyl ether and diethyl ether (Fe), methanol and acetone (Ru), and methanol, methyl formate, acetone, and hydroxyethyl formate (Os); catalytic cycles are proposed.
R. J. Daroda, J. R. Blackborow and G. Wilkinson, J. Chem. Soc., Chem. Commun., 1980, 1101 DOI: 10.1039/C39800001101
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