SCHEDULED MAINTENANCE
Deuterium exchange of certain substituted ferrocenes (under very mild basic conditions) occurs in only the substituted cyclopentadienyl-ring in nonstatistical pattern; a π→σ(η5→η1) rearrangement mechanism is proposed to account for the novel pattern of exchange.
D. W. Slocum, D. L. Beach, C. R. Ernst, R. Fellows, M. Moronski, B. Conway, J. Bencini and A. Siegel, J. Chem. Soc., Chem. Commun., 1980, 1043 DOI: 10.1039/C39800001043
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