Comparison of the photoaquation quantum yields of Cr(bpy)33+ and Cr(phen)33+ complexes in alkaline aqueous media, from direct irradiation into the spinallowed 4T2 manifold and into the spin-forbidden 2T1/2E states, indicates that the 4T2→2E intersystem-crossing (isc) yields are identical for the two complexes (ηiscca. 1).
N. Serpone, M. A. Jamieson and M. Z. Hoffman, J. Chem. Soc., Chem. Commun., 1980, 1006 DOI: 10.1039/C39800001006
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