The sodium acetate-buffered, peracetic acid oxidation of various 1-methoxybicyclo[2.2.2]oct-5-enones, prepared by hydrolysis of the adducts derived from dihydroanisole derivatives and α-chloroacrylonitrile, leads to 4-substituted cyclohex-2-en-1-one 4-acetic acid derivatives.
N. C. Madge and A. B. Holmes, J. Chem. Soc., Chem. Commun., 1980, 956 DOI: 10.1039/C39800000956
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