Issue 20, 1980

Stereochemistry of nucleophilic attack on π-allylpalladium complexes. Evidence for cis-migration of acetate from palladium to carbon

Abstract

Formation of 4-methoxycyclohex-2-enyl acetate (3) from the π-allylpalladium complex (2) shows that the acetate has attacked the π-allyl ligand from the same side as the metal (cis-addition).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 943-944

Stereochemistry of nucleophilic attack on π-allylpalladium complexes. Evidence for cis-migration of acetate from palladium to carbon

Jan-E. Bäckvall, R. E. Nordberg, E. E. Björkman and C. Moberg, J. Chem. Soc., Chem. Commun., 1980, 943 DOI: 10.1039/C39800000943

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