Synthesis, X-ray crystal structure, and magnetic and spectroscopic properties of a novel copper(I)–copper(II) cluster
Abstract
The cluster [Cu10ICu2II(C4H5N2S)12(MeCN)4][BPh4]2(MeCN)4, where C4H5N2S is the mercaptide anion of 1-methyl-2-mercaptoimidazole, presents a novel polynuclear arrangement of copper(I); the copper(II) centres of this compound display spectroscopic features similar to those observed for the copper(II) site in the blue copper proteins.
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