Precursor of an extraordinarily reactive homogeneous hydrogenation catalyst. Synthesis, X-ray crystal structure, and reactions of [closo-1,3-µ-(η2-3,4-CH2: CHCH2CH2)-3-H-3-PPh3-3,1,2-RhC2B9H10]

Mark S. Delaney; Carolyn B. Knobler; M. Frederick Hawthorne

doi:10.1039/C39800000849

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Precursor of an extraordinarily reactive homogeneous hydrogenation catalyst. Synthesis, X-ray crystal structure, and reactions of [closo-1,3-µ-(η²-3,4-CH₂: CHCH₂CH₂)-3-H-3-PPh₃-3,1,2-RhC₂B₉H₁₀]

Mark S. Delaney, Carolyn B. Knobler and M. Frederick Hawthorne

Abstract

The synthesis, X-ray crystal structure, and reactions of the catalyst precursor, the title compound (1), and the initial rates of some alkene hydrogenations catalysed by (1) are reported.

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DOI: https://doi.org/10.1039/C39800000849
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1980, 849-850

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Precursor of an extraordinarily reactive homogeneous hydrogenation catalyst. Synthesis, X-ray crystal structure, and reactions of [closo-1,3-µ-(η²-3,4-CH₂: CHCH₂CH₂)-3-H-3-PPh₃-3,1,2-RhC₂B₉H₁₀]

M. S. Delaney, C. B. Knobler and M. F. Hawthorne, J. Chem. Soc., Chem. Commun., 1980, 849 DOI: 10.1039/C39800000849

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Journal of the Chemical Society, Chemical Communications

Precursor of an extraordinarily reactive homogeneous hydrogenation catalyst. Synthesis, X-ray crystal structure, and reactions of [closo-1,3-µ-(η²-3,4-CH₂: CHCH₂CH₂)-3-H-3-PPh₃-3,1,2-RhC₂B₉H₁₀]

Abstract

Article information

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Precursor of an extraordinarily reactive homogeneous hydrogenation catalyst. Synthesis, X-ray crystal structure, and reactions of [closo-1,3-µ-(η²-3,4-CH₂: CHCH₂CH₂)-3-H-3-PPh₃-3,1,2-RhC₂B₉H₁₀]

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