Issue 17, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

Molybdenum and tungsten complexes with side-on co-ordinated SPPh2-ligands. X-Ray crystal structure determination of Mo(CO)2(PPh3)(η2-SPPh2)2.CH2Cl2

Huub P. M. M. Ambrosius,   Jan H. Noordik  and  Gerry J. A. Ariaans  

Abstract

M(CO)3Cl(η5-C5H5) and M(CO)3(PPh3)2Cl2(M = Mo, W) react with SPPh2H and Et3N to give M(CO)2-(η5-C5H5)(η2-SPPh2) and M(CO)2(PPh3)(η2-SPPh2)2, respectively; an X-ray crystal structure determination of Mo(CO)2(PPh3)(SPPh2)2 reveals a 7-co-ordinate pseudopentagonal bipyramidal geometry for the molybdenum atom with an almost planar configuration for the sulphur and phosphorus atoms.

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Article information

DOI
https://doi.org/10.1039/C39800000832
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 832-833

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Molybdenum and tungsten complexes with side-on co-ordinated SPPh2-ligands. X-Ray crystal structure determination of Mo(CO)2(PPh3)(η2-SPPh2)2.CH2Cl2

H. P. M. M. Ambrosius, J. H. Noordik and G. J. A. Ariaans, J. Chem. Soc., Chem. Commun., 1980, 832 DOI: 10.1039/C39800000832

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