The rapid absorption of one mol of dioxygen by one mol of a bi-CuI macrocyclic complex in MeCN is followed by a slower anaerobic oxidative dehydrogenation of the ligand by the bound dioxygen to regenerate the CuI centres so that the cycle may be repeated, at least once again although more slowly.
M. G. Burnett, V. McKee, S. M. Nelson and M. G. B. Drew, J. Chem. Soc., Chem. Commun., 1980, 829 DOI: 10.1039/C39800000829
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