Issue 17, 1980

A bi-copper(I)/bi-copper(II) redox cycle in the co-ordination and activation of dioxygen by a bi-copper(I) complex of a macrocyclic ligand

Abstract

The rapid absorption of one mol of dioxygen by one mol of a bi-CuI macrocyclic complex in MeCN is followed by a slower anaerobic oxidative dehydrogenation of the ligand by the bound dioxygen to regenerate the CuI centres so that the cycle may be repeated, at least once again although more slowly.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 829-831

A bi-copper(I)/bi-copper(II) redox cycle in the co-ordination and activation of dioxygen by a bi-copper(I) complex of a macrocyclic ligand

M. G. Burnett, V. McKee, S. M. Nelson and M. G. B. Drew, J. Chem. Soc., Chem. Commun., 1980, 829 DOI: 10.1039/C39800000829

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