Issue 17, 1980

Metal-catalysed reactions of benzhydryl 6-diazopenicillanate with alcohols

Abstract

Thiazepines are major products of the copper- and rhodium-catalysed reactions of benzhydryl 6-diazopenicillanate with alcohols; they are formed via rearrangement of oxonium ylide intermediates and a competing process gives the 6α-alkoxypenicillanates.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 798-799

Metal-catalysed reactions of benzhydryl 6-diazopenicillanate with alcohols

S. A. Matlin and L. Chan, J. Chem. Soc., Chem. Commun., 1980, 798 DOI: 10.1039/C39800000798

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