Kinetic measurements have been shown dioxygen to react faster with the five-co-ordinate complex [(cod)Ir(phen)I](cod = cyclo-octa-1,5-diene; phen = 1,10-phenanthroline) than with the four-co-ordinate complex [(cod)Ir(phen)]Cl to form the peroxide complex [(cod)Ir(phen)O2]X (X = Cl, I).
W. J. Louw, T. I. A. Gerber and D. J. A. de Waal, J. Chem. Soc., Chem. Commun., 1980, 760 DOI: 10.1039/C39800000760
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