Inelastic neutron scattering spectra indicate a strong vibrational coupling between NH4+ and NO3– ions in phase V of ammonium nitrate in the 500–1000 cm–1 region, although i.r. and Raman spectra show little evidence for such mixing; a variation of the coupling with the k-value may be indicated.
U. A. Jayasooriya, G. J. Kearley and S. F. A. Kettle, J. Chem. Soc., Chem. Commun., 1980, 745 DOI: 10.1039/C39800000745
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