A new approach to the interpretation of the structures of single-chain silicates is proposed, which rationalises the relationships between known regular structures and the occurrence of recently discovered defective structures in the pyroxenoid family (MSiO3) and also predicts new structures.
D. A. Jefferson and J. M. Thomas, J. Chem. Soc., Chem. Commun., 1980, 743 DOI: 10.1039/C39800000743
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