In the Diels–Alder reactions of 7,9-dimethyl-8H-cyclopent[a]acenaphthylen-8-ol (1) with several dienophiles the observed adducts arise by addition to the face of the diene bearing the hydroxy-group.
D. W. Jones, J. Chem. Soc., Chem. Commun., 1980, 739 DOI: 10.1039/C39800000739
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