The Brønsted leaving group (β1g) plot for the alkaline hydrolysis of fluorene-9-carboxylate esters in the pH region corresponding to the existence of the ester anion shows a minimum flanked by a region of high negative β1g(-1·01), corresponding to an E1cb pathway and, for esters of pK1g > 9·5, a region of positive β1g(+0·11).
M. Alborz and K. T. Douglas, J. Chem. Soc., Chem. Commun., 1980, 728 DOI: 10.1039/C39800000728
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