7  Li–13C n.m.r. coupling constants and the nature of the carbon–lithium bond: INDO MO calculations

Timothy Clark; Jayaraman Chandrasekhar; Paul von Ragué Schleyer

doi:10.1039/C39800000672

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⁷Li–¹³C n.m.r. coupling constants and the nature of the carbon–lithium bond: INDO MO calculations

Timothy Clark, Jayaraman Chandrasekhar and Paul von Ragué Schleyer

Abstract

INDO molecular orbital calculations suggest that the ⁷Li–¹³C n.m.r. coupling constant for the methyl-lithium monomer should be very large; this indicates the predominantly covalent character of the C–Li bond.

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DOI: https://doi.org/10.1039/C39800000672
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1980, 672-673

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⁷ Li–¹³C n.m.r. coupling constants and the nature of the carbon–lithium bond: INDO MO calculations

T. Clark, J. Chandrasekhar and P. V. R. Schleyer, J. Chem. Soc., Chem. Commun., 1980, 672 DOI: 10.1039/C39800000672

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Journal of the Chemical Society, Chemical Communications