Issue 13, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and structure (X-ray diffraction and spectroscopy) of an extremely rigid and non-fluxional trinuclear trihydride, [Rh3H3(η5-C5Me5)3O]PF6·H2O

Andrew Nutton,   Pamela M. Bailey,   Neil C. Braund,   Robin J. Goodfellow,   Roger S. Thompson  and  Peter M. Maitlis  

Abstract

The trinuclear trihydride [Rh3H3(η5-C5Me5)3O]·PF6·H2O has been synthesised and characterised by X-ray diffraction and spectroscopy; the 1H n.m.r. spectrum shows the molecule to be extremely rigid with a minimumΔG‡ for fluxionality of 109 kJ mol–1.

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Article information

DOI
https://doi.org/10.1039/C39800000631
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 631-633

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Synthesis and structure (X-ray diffraction and spectroscopy) of an extremely rigid and non-fluxional trinuclear trihydride, [Rh3H3(η5-C5Me5)3O]PF6·H2O

A. Nutton, P. M. Bailey, N. C. Braund, R. J. Goodfellow, R. S. Thompson and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1980, 631 DOI: 10.1039/C39800000631

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