Issue 13, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

The synthesis and molecular structure of 9-H-9,9-(Et3P)2-µ10,11-H-7,8,9-C2PtB8H10 and 9-H-9,10-(Et3P)2-7,8,9-C2PtB8H9; Pt(9)→ B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt0→ PtIV→ PtII

Geoffrey K. Barker,   Michael Green,   F. Gordon A. Stone,   Alan J. Welch  and  Wayne C. Wolsey  

Abstract

Reaction of [Pt2(µ-cyclo-octa-1,5-diene)(PEt3)4] with 5,6-dicarba-nido-decaborane affords 9-H-9,9-(Et3P)2-µ10,11-H-7,8,9-C2PtB8H10, which on pyrolysis (100 °C) loses H2 and forms 9-H-9,10-(Et3P)2-7,8,9-C2PtB8H9; the structures of these compounds have been determined by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/C39800000627
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 627-629

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The synthesis and molecular structure of 9-H-9,9-(Et3P)2-µ10,11-H-7,8,9-C2PtB8H10 and 9-H-9,10-(Et3P)2-7,8,9-C2PtB8H9; Pt(9)→ B(10) migration of a triethylphosphine ligand, and evidence for the redox sequence Pt0→ PtIV→ PtII

G. K. Barker, M. Green, F. G. A. Stone, A. J. Welch and W. C. Wolsey, J. Chem. Soc., Chem. Commun., 1980, 627 DOI: 10.1039/C39800000627

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