SCHEDULED MAINTENANCE
Oxidation of (η5-C5H5)Rh(PPh3)2 by silver ion results in coupling of cyclopentadienyl ligands to give fulvalene–dirhodium(II) complexes; semi-empirical MO calculation give insight into the reaction sequence and allow a rational extension to the coupling reaction of a co-ordinated allyl ligand to give a hexa-1,5-diene complex.
R. J. McKinney, J. Chem. Soc., Chem. Commun., 1980, 603 DOI: 10.1039/C39800000603
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