The transition metal carbonyls M(CO)6(M = Cr, Mo, and W) and M3(CO)12(M = Ru and Os), but not Fe(CO)5, have been found to be active homogeneous catalysts for the water gas shift reaction in the presence of a large excess of sulphides generated by sodium sulphide dissolved in aqueous methanol.
A. D. King, R. B. King and D. B. Yang, J. Chem. Soc., Chem. Commun., 1980, 529 DOI: 10.1039/C39800000529
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