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Non-linear Hammett plots: a non-traditional interpretation
Abstract
In a two-step reaction, a curvature of the Hammett plot will be observed if one of the sub-rate constants reaches the diffusion-controlled region owing to changes in substituents.
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Article information
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J. Chem. Soc., Chem. Commun., 1980, 453-454
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Non-linear Hammett plots: a non-traditional interpretation
S. Hoz and M. Ben-Zion, J. Chem. Soc., Chem. Commun., 1980, 453 DOI: 10.1039/C39800000453
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