SCHEDULED MAINTENANCE
Prochiral silaethylene intermediates react with chiral alcohols to give unequal amounts of diastereomeric pairs of alkoxysilanes (up to 30% enantiomeric excess); this is the first example of asymmetric induction observed at a silicon centre involving a trigonal silicon species.
G. Bertrand, J. Dubac, P. Mazerolles and J. Ancelle, J. Chem. Soc., Chem. Commun., 1980, 382 DOI: 10.1039/C39800000382
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