Issue 1, 1980

Bis-µ-(2,3,4-η3-nido-hexaboranyl)-bis(dimethylphenylphosphine)diplatinum(Pt–Pt), [Pt23-B6H9)2(PMe2Ph)2], an unexpected product from the reaction of (B10H13)2O with [PtCl2(PMe2Ph)2]; crystal and molecular structure

Abstract

One of the products from the reaction of 6,6′-(B10H13)2O with cis-[PtCl2(PMe2Ph)2]is [Pt2(η3-B6H9)2(PMe2Ph)2], which is shown by X-ray crystallography to have a Pt–Pt bond with two bridging bidentate η3-nido-hexaboranate ligands.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 37b-38

Bis-µ-(2,3,4-η3-nido-hexaboranyl)-bis(dimethylphenylphosphine)diplatinum(Pt–Pt), [Pt23-B6H9)2(PMe2Ph)2], an unexpected product from the reaction of (B10H13)2O with [PtCl2(PMe2Ph)2]; crystal and molecular structure

N. N. Greenwood, M. J. Hails, J. D. Kennedy and W. S. McDonald, J. Chem. Soc., Chem. Commun., 1980, 37b DOI: 10.1039/C3980000037B

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