Issue 8, 1980

Diene geometry and allylic axial chirality effect

Abstract

The sense of the contribution of polarizable allylic axial bonds to the ππ* Cotton effect of dienes is found to be determined by the chirality of the system which is defined by the direction of the transition moment and direction of the allylic bond.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 346-347

Diene geometry and allylic axial chirality effect

J. Gawronski and K. Gawronska, J. Chem. Soc., Chem. Commun., 1980, 346 DOI: 10.1039/C39800000346

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