Issue 7, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

Dynamic n.m.r. behaviour of {6,7,8,9-η4-nido-decaborato(2–)}bis(dimethylphenylphosphine)platinum(II), [Pt(η4-B10H12)(PMe2Ph)2]; a novel type of metalloborane fluxionality

Simon K. Boocock,   Norman N. Greenwood  and  John D. Kennedy  

Abstract

Variable temperature 1H–{31P} and 1H–{11B} n.m.r. spectroscopy show that the [η4-B10H12]2– ligand in [Pt(B10H12)(PMe2Ph)2] undergoes a novel type of nondissociative rotation about an axis approximately in the PtII co-ordination plane; ΔG‡ for the process is 79 ± 5 kJ mol–1 at 71 °C.

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Article information

DOI
https://doi.org/10.1039/C39800000305
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 305-306

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Dynamic n.m.r. behaviour of {6,7,8,9-η4-nido-decaborato(2–)}bis(dimethylphenylphosphine)platinum(II), [Pt(η4-B10H12)(PMe2Ph)2]; a novel type of metalloborane fluxionality

S. K. Boocock, N. N. Greenwood and J. D. Kennedy, J. Chem. Soc., Chem. Commun., 1980, 305 DOI: 10.1039/C39800000305

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