Issue 5, 1980
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of the carbido cluster [Os10(CO)24C]2– and the X-ray structure of [Os10(CO)24C][(Ph3P)2N]2

Peter F. Jackson,   Brian F. G. Johnson,   Jack Lewis,   Mary McPartlin  and  William J. H. Nelson  

Abstract

The carbido dianion [Os10(CO)24C]2– has been isolated from the pyrolysis of Os3(CO)11(py)(py = pyridine), and the pyrolysis of Os3(CO)12; an X-ray structural analysis of the [(Ph3P)2N]+ salt has shown a tetrahedral arrangement of ten metal atoms that is a fragment of a cubic close packed array.

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Article information

DOI
https://doi.org/10.1039/C39800000224
Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 224-226

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Synthesis of the carbido cluster [Os10(CO)24C]2– and the X-ray structure of [Os10(CO)24C][(Ph3P)2N]2

P. F. Jackson, B. F. G. Johnson, J. Lewis, M. McPartlin and W. J. H. Nelson, J. Chem. Soc., Chem. Commun., 1980, 224 DOI: 10.1039/C39800000224

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