High-yield reactions of unsaturated thiirans with halogens or SCl2 proceed by initial electrophilic attack on sulphur and furnish halogeno-sulphides, in some cases via isolable disulphides, thereby providing a novel method of creating an intramolecular disulphide link.
P. H. McCabe and A. Stewart, J. Chem. Soc., Chem. Commun., 1980, 100 DOI: 10.1039/C39800000100
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