Reduction of the trans-2-enoyl intermediate (1) to give the saturated alkyl thioester (2) in fatty acid biosynthesis occurs by means of an anti-addition of hydrogen to the pro-2S and pro-3S position of the carbons forming the double bond.
B. Sedgwick and C. Morris, J. Chem. Soc., Chem. Commun., 1980, 96 DOI: 10.1039/C39800000096
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