Deprotonation of pinacol trimethylsilylmethaneboronate yields an anion which reacts with carbonyl compounds to form alkeneboronic esters, or with alkyl halides to form α-trimethylsilylalkaneboronic esters.
D. S. Matteson and D. Majumdar, J. Chem. Soc., Chem. Commun., 1980, 39 DOI: 10.1039/C39800000039
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