Issue 1, 1980

Protonated dimethyl sulphoxide, [Me2SO ⋯ H ⋯ OSMe2]+; a novel hydrogen-bridged structure: X-ray crystal structure of trans-[H(Me2SO)2][RhCl4(Me2SO)2]

Abstract

Studies on salts of tetrachlororhodate(III) containing sulphoxide ligands show the existence of the hydrogen-bonded cation [Me2SO ⋯ H ⋯ OSMe2]+ with a very short O ⋯ H ⋯ O bond length of 2·42 Å.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 31-32

Protonated dimethyl sulphoxide, [Me2SO ⋯ H ⋯ OSMe2]+; a novel hydrogen-bridged structure: X-ray crystal structure of trans-[H(Me2SO)2][RhCl4(Me2SO)2]

B. R. James, R. H. Morris, F. W. B. Einsten and A. Willis, J. Chem. Soc., Chem. Commun., 1980, 31 DOI: 10.1039/C39800000031

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