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Issue 4, 1979
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Pressure and solvent effects on the cycloaddition reactions between substituted nitrosobenzenes and butadiene derivatives

Abstract

The cycloaddition reactions of 2,3-dimethylbutadiene with 4-chloro-1-nitrosobenzene and 4-ethoxy-1-nitrosobenzene and of cyclopentadiene with 4-chloro-1-nitrosobenzene were investigated as a function of temperature, solvent, and pressure. Rate constants, activation parameters, and volumes of reactions were evaluated. The data support a one-step mechanism for the cyclizations.

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J. Chem. Soc., Perkin Trans. 2, 1979, 519-524
Article type
Paper

Pressure and solvent effects on the cycloaddition reactions between substituted nitrosobenzenes and butadiene derivatives

G. Swieton and H. Kelm, J. Chem. Soc., Perkin Trans. 2, 1979, 519
DOI: 10.1039/P29790000519

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