Issue 4, 1979

Pressure and solvent effects on the cycloaddition reactions between substituted nitrosobenzenes and butadiene derivatives

Abstract

The cycloaddition reactions of 2,3-dimethylbutadiene with 4-chloro-1-nitrosobenzene and 4-ethoxy-1-nitrosobenzene and of cyclopentadiene with 4-chloro-1-nitrosobenzene were investigated as a function of temperature, solvent, and pressure. Rate constants, activation parameters, and volumes of reactions were evaluated. The data support a one-step mechanism for the cyclizations.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1979, 519-524

Pressure and solvent effects on the cycloaddition reactions between substituted nitrosobenzenes and butadiene derivatives

G. Swieton and H. Kelm, J. Chem. Soc., Perkin Trans. 2, 1979, 519 DOI: 10.1039/P29790000519

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