The 13C n.m.r. spectrum of triamantane (3) observed at 22.64 and 62.8 MHz is assigned using selective 1H decoupling. Internal strain causing geometrical distortions at the quaternary carbon leads to a non-additive down-field shift of its signal.
M. Dheu, D. Gagnaire, H. Duddeck, F. Hollowood and M. A. McKervey, J. Chem. Soc., Perkin Trans. 2, 1979, 357 DOI: 10.1039/P29790000357
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