Issue 0, 1979

Diterpene synthesis. Part 1. Copper(I)-catalysed 1,6-addition of a benzyl grignard reagent to a dienone

Abstract

Copper(I) salts catalyse the 1,6-conjugate addition reaction of m- and p-methoxybenzylmagnesium halides to the monocyclic linear dienone (6) at the expense of 1,2- and 1,4-addition. An improved synthesis of the dienone is reported.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1979, 2840-2844

Diterpene synthesis. Part 1. Copper(I)-catalysed 1,6-addition of a benzyl grignard reagent to a dienone

B. R. Davis and S. J. Johnson, J. Chem. Soc., Perkin Trans. 1, 1979, 2840 DOI: 10.1039/P19790002840

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements