Isomeric 2′- and 3′-O-t-butyidimethylsilylribonucleoside derivatives (2) and (3) undergo interconversion by a first-order equilibration reaction. This intramolecular reaction takes place particularly readily in methanol solution and in the presence of base.
S. S. Jones and C. B. Reese, J. Chem. Soc., Perkin Trans. 1, 1979, 2762 DOI: 10.1039/P19790002762
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