The 5-endo-7-anti-disubstituted bicyclo[2.2.1]heptan-2-ones (1)–(5) afforded the aldehydes (6)–(10) respectively on photolysis. The hydroxy-aldehyde (10) is a known intermediate in the synthesis of prostaglandin-C2. The aldehydes (7)–(9) were converted into the 11,12-dehydroprostaglandin-F2α derivatives (14)–(18).
N. M. Crossland, S. M. Roberts and R. F. Newton, J. Chem. Soc., Perkin Trans. 1, 1979, 2397 DOI: 10.1039/P19790002397
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