Ketones have shown to be useful vinylating agents of phenols. They react with aluminium phenoxides in xylene under reflux to give isomerically pure ortho-vinylphenol derivatives (3), in high yields.
G. Casiraghi, G. Casnati, G. Sartori and L. Bolzoni, J. Chem. Soc., Perkin Trans. 1, 1979, 2027 DOI: 10.1039/P19790002027
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