L-Prolyl-L-valyl-2-methylalaninyl-2-methylalanine has been synthesised in 33% overall yield on the 100 g scale, from benzyloxycarbonyl-L-proline.
I. M. Shaw and A. Taylor, J. Chem. Soc., Perkin Trans. 1, 1979, 1866 DOI: 10.1039/P19790001866
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