Synthesis and reactions of sulphuryl azide, and aryl and 7,7-dimethylnorbornan-1-yl azidosulphates

Abstract

Sulphuryl azide can be made safely and efficiently by the reaction in aceton itrile of sodium azide with sulphury chloride in the presence of pyridine. The reactions of solutions of sulphuryl azide with trivalent phosphorus com pounds, enamines, norbornene, and dibenzoylmethane have been studied. The synthesis and reactions of 7,7-dimethylnorbornan-1-yl and p-nitrophenyl and phenyl azidosulphates have been investigated.