The kinetic resolution of the unsaturated sulphoximides (6)–(10)via addition of the chiral amines (11)–(13) has been examined. The rate of reaction depends strongly on steric effects, to the point that a different reaction, involving breaking of the S–N bond, may occur.
R. Annunziata and M. Cinquini, J. Chem. Soc., Perkin Trans. 1, 1979, 1684 DOI: 10.1039/P19790001684
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